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Fragmentation (mass spectrometry)
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Fragmentation (mass spectrometry) : ウィキペディア英語版
Fragmentation (mass spectrometry)

In mass spectrometry, fragmentation is the dissociation of energetically unstable molecular ions formed from passing the molecules in the ionization chamber of a mass spectrometer. The fragments of a molecule cause a pattern in the mass spectrum used to determine structural information of the molecule.
== Mass spectrometry techniques ==
Fragmentation can occur in the ion source (in-source fragmentation) where it is generally not a desired effect. Ion source conformation is an important criterion in the level of fragmentation observed.
Desired fragmentation is made in the collision zone (post-source fragmentation) of a tandem mass spectrometer. It is a part of gas phase ion chemistry and there are different types of mass fragmentation:
collision-induced dissociation (CID),
electron-capture dissociation (ECD),
electron-transfer dissociation (ETD),
negative electron-transfer dissociation (NETD),
electron-detachment dissociation (EDD),
photodissociation, particularly infrared multiphoton dissociation (IRMPD) and blackbody infrared radiative dissociation (BIRD),
surface-induced dissociation (SID),
Higher-energy C-trap dissociation (HCD),
charge remote fragmentation.

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